Superman has one DUPLO set, 10543 Superman Rescue from 2014. It has a DUPLO Superman figure, a small car, a fire hydrant and a simple office build with Daily Planet signage. The scene is Superman stopping the car beside the hydrant.
1 set

10543 Superman Rescue

Theme / Subtheme Duplo / Superman
Year 2014
Pieces / Duplo figures 19 / 1
Availability Retired
10543 LEGO Duplo Superman Rescue
Retail $19.99
Value $86.00
Growth  +330.2%
Annual growth 8.3%